Two Reasons Why Lithium-Ion Batteries Fail

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We are curating a thought-provoking article by Dr Matthew Priestley. He is an associate lecturer at Energy Systems Research Group at University of New South Wales, Australia. His thinking goes further than pondering why lithium-ion batteries fail. We discussed his two ways to make lithium-ion batteries safer in our previous post. Now we move on to the root causes of occasional, catastrophic failure.

Two Main Causes Why Lithium-Ion Batteries Fail

REASON ONE: Lithium Batteries’ Particular Hazards

Matthew Priestley confirms “all types of batteries can be hazardous and can pose a safety risk”. However, lithium-ion’s particular threat is its electrolyte comprises lithium salts, in a solvent solution that might include ethylene carbonate. This liquid electrolyte is highly effective. However, it is also highly volatile, and flammable Matthew Priestley says.

There are various reasons why lithium-ion batteries fail. Their volatility increases in high ambient temperatures. Moreover, the batteries also become naturally warmer while delivering power. Those factors can set the stage for uncontrolled meltdown, if the battery fails, or becomes damaged in some way.

REASON TWO: Technical Reasons Why Lithium-Ion Batteries Fail

However, those stage-setting conditions we referred to are insufficient cause for lithium-ion failure in themselves. The technology is solid, and designed to stay safe. Here are the four main out-of-specification reasons why lithium-ion batteries fail according to Matthew Priestley:

  1. Physical damage to the battery exposing the weakness of the volatile electrolyte.
  2. A short circuit agitating the chemistry and leading to sudden temperature rise.
  3. Excessive heat from overcharging the battery / using a faulty battery charger.
  4. The heat combining with the chemicals to cause a self-fulfilling fire.

The above reasons for lithium-ion battery failure are largely in the hands of the user. Put simply, it is largely up to you to protect your lithium-ion battery, and its device from damage and / or overheating, and to recharge it correctly. We’ll leave you with that thought, as we prepare the next post.

More Information

Two Ways to Make Lithium Batteries Safer

Battery Management System Fundamentals

Preview Image:  Thin Film Lithium-Ion Battery

University of New South Wales in Australia Post

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About Author

Electricity has always intrigued me. I have been writing about batteries and energy storage for more than ten years, and have published over 4,000 articles on this website. During that time, I have researched developments across lead-acid, lithium-ion, sodium-ion, flow batteries, and emerging energy-storage technologies. My goal is to explain complex battery concepts in clear, practical language that anyone can understand. My writing career began unexpectedly after leaving the corporate world. What started as a search for a new direction gradually became a fascination with batteries, renewable energy, and the science that powers modern life. Writing may not have made me wealthy, but it has given me the opportunity to explore an industry that continues to evolve in remarkable ways.

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