The World’s First Flow Battery in 1879

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We introduced John Doyle’s remarkable invention in our previous post – see link below. There, we defined the various parts, and how a pump replenished the ‘excitant’ fluid. Today we move on to describing the operation of the world’s first flow battery in more detail. Time may yet prove this was one of the most important moments in energy storage history.

Operating Principles of the World’s First Flow Battery

PART OF THE FLOW BATTERY

john doyle
John Doyle’s Flow Battery (Patent Image Storage BY U.S. Government Document)
  • ‘A’ is a plain jar containing ‘B’, a ‘cleft zinc plate that connects to the first circuit wire.
  • Two or more porous jars ‘C’ sit within this, each containing a ‘D’ electro-negative plate.
  • Each electro-negative plate has a coupling wire D1. These connect to the second circuit wire.
  • ‘E’ is a suitable reservoir for ‘excitant’ supply. A feed-pipe ‘F’ connects it to the flow battery.
  • There, the ‘excitant’ flows via a funnel E1 or ‘hopper’ sealed onto the mouth of the porous jars.

EXCITANT DELIVERY MECHANISM

  • The top of the reservoir ‘E’ contains a protruding tube ‘a’ having a conical bore profile.
  • A vertical plug ‘b’ with a matching profile fits precisely into this without possibility of leakage.
  • The plug locates inside the arm of a ‘vertically-vibrating’ lever ‘G’ exerting sufficient fulcrum.
  • A clockwork mechanism ‘H’ automatically moves this fulcrum via a single or double cam ‘I’.
  • This cam depresses the lever ‘G’ intermittently, causing the plug ‘b’ to lift on each occasion.
  • This allows air to enter reservoir ‘E’ and in turn allow an amount of ‘excitant’ to enter the porous jars.
  • The cam ‘I’ rotates once per hour with a single tooth. This rate increases by adding teeth.
  • Waste pipes ‘L’ carry ‘expended or partly-expended excitant’ to a separate storage vessel ‘K’.
  • This liquid may then be replenished by addition of chemicals according to requirements.

We’ll wrap this up in a third article shortly. We do hope you are finding this interesting!

More Information

First Flow Battery By John Doyle

Battery Carbon Footprints Becoming Critical

Preview Image: John Doyle’s Flow Battery

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About Author

Electricity has always intrigued me. I have been writing about batteries and energy storage for more than ten years, and have published over 4,000 articles on this website. During that time, I have researched developments across lead-acid, lithium-ion, sodium-ion, flow batteries, and emerging energy-storage technologies. My goal is to explain complex battery concepts in clear, practical language that anyone can understand. My writing career began unexpectedly after leaving the corporate world. What started as a search for a new direction gradually became a fascination with batteries, renewable energy, and the science that powers modern life. Writing may not have made me wealthy, but it has given me the opportunity to explore an industry that continues to evolve in remarkable ways.

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